AIPMT PRELIMS2005Chemistry-Solutions

AIPMT PRELIMS 2005 Chemistry Raoult's Law MCQ Question

Type: MCQ-numerical-Hard-Class 12

A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of the pure hydrocarbons at 20°C are 440 mm of Hg for pentane and 120 mm of Hg for hexane. The mole fraction of pentane in the vapour phase would be:

A

0.178

B

0.278

C

0.378

D

0.478

Correct Answer

Option D

Detailed Explanation

Using Raoult's law and Dalton's law, the partial pressure of pentane is calculated, and the mole fraction in the vapour phase is determined using the total pressure.

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