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AIPMT Prelims Chemistry Class 12 Questions

256 questions

CH₃CHO and C₂H₅CH₂CHO can be distinguished chemically by

2012MCQmedium

Pₐ and P_b are the vapour pressures of pure liquid components A and B, respectively of an ideal binary solution. If xₐ represents the mole fraction of component A, the total pressure of the solution will be

2012MCQmedium

In the following reaction:

2012MCQmedium

Limiting molar conductivity of NH₄OH (i.e., Λₘ(NH₄OH)) is equal to:

2012MCQmedium

Buffer solutions have constant acidity and alkalinity because:

2012MCQmedium

Deficiency of vitamin B₁ causes the disease

2012MCQeasy

Which one of the following statements is incorrect about enzyme catalysis?

2012MCQeasy

In a reaction, A + B → Product, rate is doubled when the concentration of B is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (A and B) are doubled, rate law for the reaction can be written as:

2012MCQhard

Which one of the following sets of monosaccharides forms sucrose?

2012MCQmedium

In a zero-order reaction for every 10° rise of temperature, the rate is doubled. If the temperature is increased from 10°C to 100°C, the rate of the reaction will become:

2012MCQmedium

Which of the statements is not true?

2012MCQmedium

Which one of the following is an outer orbital complex and exhibits paramagnetic behaviour?

2012MCQmedium

Given below is the diagrammatic representation of one of the categories of small molecular weight organic compounds in the living tissues. Identify the category shown and the one blank component “X” in it.

2012MCQhard

The electrode potentials for Cu²⁺(aq) + e⁻ → Cu⁺(aq) and Cu⁺(aq) + e⁻ → Cu(s) are +0.15 V and +0.50 V respectively. The value of E° for Cu²⁺/Cu will be

2011MCQmedium

Mole fraction of the solute in a 1.00 molal aqueous solution is

2011MCQmedium

The van't Hoff factor i for a compound which undergoes dissociation in one solvent and association in other solvent is respectively

2011MCQmedium

Standard electrode potential for Sn⁴⁺/Sn²⁺ couple is +0.15 V and that for the Cr³⁺/Cr couple is −0.74 V. These two couples in their standard state are connected to make a cell. The cell potential will be

2011MCQmedium

If the E°cell for a given reaction has a negative value, then which of the following gives the correct relationships for the values of ΔG° and Keq?

2011MCQmedium

The freezing point depression constant for water is –1.86°Cm⁻¹. If 5.00 g Na₂SO₄ is dissolved in 45.0 g H₂O, the freezing point is changed by –3.82°C. Calculate the van't Hoff factor for Na₂SO₄.

2011MCQmedium

Standard electrode potential of three metals X, Y and Z are –1.2 V, +0.5 V and –3.0 V respectively. The reducing power of these metals will be

2011MCQmedium

Which one of the following statements for the order of a reaction is incorrect?

2011MCQeasy

For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation state will be there in which of the following order?

2011MCQmedium

The complex, [Pt (Py) (NH₃) Br Cl ] will have how many geometrical isomers?

2011MCQmedium

The complexes [Co(NH₃)₆] [Co(CN)₆] are the examples of which type of isomerism?

2011MCQmedium

The d-electron configurations of Cr²⁺, Mn²⁺, Fe²⁺ and Co²⁺ are d⁴, d⁵, d⁶ and d⁷ respectively. Which one of the following will exhibit minimum paramagnetic behaviour?

2011MCQmedium

Of the following complex ions, which is diamagnetic in nature?

2011MCQmedium

In a set of reactions m-bromobenzoic acid gave a product D. Identify the product D.

[Image of reaction sequence: m-bromobenzoic acid with SOCl₂, NH₃, NaOH, Br₂]

2011MCQhard

Which one is a nucleophilic substitution reaction among the following?

2011MCQmedium

The Lassaigne's extract is boiled with conc. HNO₃ while testing for halogens. By doing so it.

2011MCQmedium

Clemmensen reduction of a ketone is carried out in the presence of which of the following?

2011MCQmedium

Which one of the following statements is not true regarding (+) Lactose?

2011MCQmedium

Which one of the following structural formulae of two organic compounds is correctly identified along with its related function?

2011MCQmedium

An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to

2010MCQmedium

25.3 g of sodium carbonate, Na₂CO₃ is dissolved in enough water to make 250 mL of solution. If sodium carbonate dissociates completely, molar concentration of sodium ion, Na⁺ and carbonate ions, CO₃²⁻ are respectively (Molar mass of Na₂CO₃ = 106 g mol⁻¹)

2010MCQmedium

An aqueous solution is 1.00 molal in KI. Which change will cause the vapour pressure of the solution to increase?

2010MCQmedium

For the reaction N₂O₅(g) → 2NO₂(g) + 1/2 Ω₂(g) the value of rate of disappearance of N₂O₅ is given as 6.25 × 10⁻³ mol L⁻¹s⁻¹. The rate of formation of NO₂ and O₂ is given respectively as:

2010MCQmedium

During the kinetic study of the reaction 2A + B → C + D, following results were obtained:

2010MCQmedium

For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46 V at 25°C. The value of standard Gibbs energy, ΔG⁰ will be (F = 96500 C mol⁻¹)

2010MCQmedium

For an endothermic reaction, energy of activation is Eₐ and enthalpy of reaction is ΔH (both of these in kJ/mol). Minimum value of Eₐ will be

2010MCQmedium

Which one of the following ions has electronic configuration [Ar]₃d⁶?

2010MCQmedium

Which of the following ions will exhibit colour in aqueous solutions?

2010MCQmedium

Which of the following complex ion is not expected to absorb visible light?

2010MCQmedium

The existence of two different coloured complexes with the composition of [Co(NH₃)₄Cl₂]⁺ is due to

2010MCQmedium

Oxidation states of phosphorus in H₄P₂O₅, H₄P₂O₆ and H₄P₂O₇ are respectively

2010MCQmedium

Crystal field stabilization energy for high spin d⁴ octahedral complex is

2010MCQmedium

Aniline in a set of the following reactions yielded a coloured product Y. The structure of Y would be

2010MCQhard

The reaction of toluene with Cl₂ in presence of FeCl₃ gives X and reaction in presence of light gives Y. Thus, X and Y are

2010MCQmedium

Which one of the following does not exhibit the phenomenon of mutarotation?

2010MCQmedium

Which of these is most reactive towards Sₙ1 reaction?

2010MCQmedium

Which of the following statements for tertiary amines is ‘False’?

2010MCQmedium

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