AIPMT PRELIMS2011Chemistry-Coordination Compounds

AIPMT PRELIMS 2011 Chemistry Magnetic Properties MCQ Question

Type: MCQ-conceptual-Medium-Class 12

The d-electron configurations of Cr²⁺, Mn²⁺, Fe²⁺ and Co²⁺ are d⁴, d⁵, d⁶ and d⁷ respectively. Which one of the following will exhibit minimum paramagnetic behaviour?

A

[Cr(H₂O)₆]²⁺

B

[Mn(H₂O)₆]²⁺

C

[Fe(H₂O)₆]²⁺

D

[Co(H₂O)₆]²⁺

Correct Answer

Option D

Detailed Explanation

Co²⁺ has the electron configuration 3d⁷ 4s⁰, which results in the minimum number of unpaired electrons, making it the least paramagnetic.

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