AIPMT PRELIMS2005Chemistry-Coordination Compounds

AIPMT PRELIMS 2005 Chemistry Crystal Field Theory MCQ Question

Type: MCQ-conceptual-Medium-Class 12

Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic no.: Zn = 30, Cr = 24, Co = 27, Ni = 28)

A

[Zn (NH₃)₆]²⁺

B

[Cr (NH₃)₆]³⁺

C

[Co (NH₃)₆]³⁺

D

[Ni (NH₃)₆]²⁺

Correct Answer

Option C

Detailed Explanation

[Ni (NH₃)₆]²⁺ is an inner orbital complex with d²sp³ hybridization and is diamagnetic due to paired electrons.

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