AIPMT MAINS2012Chemistry-Coordination Compounds

AIPMT MAINS 2012 Chemistry Complex Geometry MCQ Question

Type: MCQ-conceptual-Medium-Class 12

Red precipitate is obtained when ethanol solution of dimethylglyoxime is added to ammoniacal Ni(II). Which of the following statements is not true?

Question diagram
A

Red complex has a square planar geometry.

B

Complex has symmetrical H⁻bonding.

C

Red complex has a tetrahedral geometry.

D

Dimethylglyoxime functions as bidentate ligand.

Correct Answer

Option C

Detailed Explanation

The red complex formed with dimethylglyoxime and Ni(II) is square planar, not tetrahedral.

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