STANDARDChemistry-Chemical Bonding and Molecular Structure

STANDARD Chemistry Isostructural Species MCQ Question

Type: MCQ-conceptual-Medium-Class 11

Isostructural species are those which have the same shape and hybridisation. Among the given species, identify the isostructural pairs.

A

[NF₃ and BF₃]

B

[BF₄⁻ and NH₄⁺]

C

[BCl₃ and BrCl₃]

D

[NH₃ and NO₃⁻]

Correct Answer

Option B

Detailed Explanation

NF₃ (pyramidal) and BF₃ (trigonal planar) are not isostructural. BF₄⁻ (tetrahedral) and NH₄⁺ (tetrahedral) are isostructural. BCl₃ (trigonal planar) and BrCl₃ (trigonal bipyramidal) are not isostructural. NH₃ (pyramidal) and NO₃⁻ (trigonal planar) are not isostructural. Thus, BF₄⁻ and NH₄⁺ are isostructural species.

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