MarksRiser
MarksRiser
RE-NEET2026Chemistry-Redox Reactions

RE-NEET 2026 Chemistry Titration MCQ Question

Type: MCQ-numerical-Medium-Class 11

In an acidic medium, 10 mL of 0.25 M oxalic acid is titrated with KMnO₄ solution. If the volume of KMnO₄ solution required to reach end point is 10 mL, the strength of the KMnO₄ solution is

A

0.20 M

B

0.25 M

C

0.15 M

D

0.10 M

Correct Answer

Option D

Detailed Explanation

In a redox titration involving oxalic acid and KMnO₄, the balanced reaction shows that 5 moles of oxalic acid react with 2 moles of KMnO₄.

First, calculate the moles of oxalic acid:

Moles of oxalic acid=Volume (L)×Molarity=0.010 L×0.25 M=0.0025 mol\text{Moles of oxalic acid} = \text{Volume (L)} \times \text{Molarity} = 0.010 \, \text{L} \times 0.25 \, \text{M} = 0.0025 \, \text{mol}

Using the stoichiometry of the reaction:

Moles of KMnO₄=25×Moles of oxalic acid=25×0.0025=0.001 mol\text{Moles of KMnO₄} = \frac{2}{5} \times \text{Moles of oxalic acid} = \frac{2}{5} \times 0.0025 = 0.001 \, \text{mol}

Now, calculate the molarity of KMnO₄:

Molarity of KMnO₄=MolesVolume (L)=0.001 mol0.010 L=0.10 M\text{Molarity of KMnO₄} = \frac{\text{Moles}}{\text{Volume (L)}} = \frac{0.001 \, \text{mol}}{0.010 \, \text{L}} = 0.10 \, \text{M}

Thus, the strength of the KMnO₄ solution is 0.10 M. Other options fail because they do not align with the stoichiometric calculations based on the reaction.

Found an issue with this question?