Chemistry-Isomerism in Complexes

NEET Chemistry Isomerism in Complexes MCQ Question

Type: MCQ-diagram based-Hard-Class 12

Consider an octahedral complex of the form [Ma3b3] where ligands a and b are different. If three identical ligands occupy positions at the corners of one octahedral face, what type of isomer is this?

Question diagram
A

Facial (fac) isomer

B

Meridional (mer) isomer

C

Linkage isomer

D

Ionisation isomer

Correct Answer

Option A

Detailed Explanation

In octahedral complexes of the type [Ma3b3], when three identical ligands occupy adjacent positions at the corners of an octahedral face, the isomer is termed a facial (fac) isomer. This is based on the description of geometrical isomerism in the NCERT context.

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