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NEET Chemistry Coordination Compounds Class 12 Questions

248 questions

Which of the following complexes formed by Cu²⁺ ions is most stable?

MCQmedium

Indicate the complex ion which shows geometrical isomerism.

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The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of transition element, which shows highest magnetic moment.

MCQmedium

The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr³⁺ ion is

MCQmedium

The correct IUPAC name of [Pt(NH₃)₂Cl₂] is

MCQeasy

Assertion : Co(IV) is known but Ni(IV) is not. Reason : Ni(IV) has d⁴ electronic configuration.

Assertion Reasonhard

Assertion (A): [Fe(CN)₆]³⁻ ion shows magnetic moment corresponding to two unpaired electrons.

Reason (R): Because it has d²sp³ type hybridisation.

Assertion Reasonmedium

Weak field ligands form high spin complexes due to (where Δ₀ is crystal field splitting and P = pairing energy)

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Which of the following statements is correct about [Co(H₂O)₆]²⁺ complex?

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[Co(NH₃)Cl(en)]²⁺ shows two geometrical isomers cis and trans. Which of the following statements is correct?

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Give reason for the statement, [Ni(CN)₄]²⁻ is diamagnetic while [NiCl₄]²⁻ is paramagnetic in nature.

MCQhard

In the following question, a statement of assertion is followed by a statement of reason. Mark the correct choice. Assertion: [Cu(NH₃)₄]²⁺ is coloured while [Cu(CN)₄]³⁻ is colourless. Reason: [Cu(NH₃)₄]²⁺ has dsp² hybridization.

Assertion Reasonmedium

Assertion : K₂[Ni(EDTA)] is more stable than K₃[Al(C₂O₄)₃]. Reason : Ni is a transition element while Al is a non-transition element.

Assertion Reasonmedium

Which one of the following complexes will have four isomers?

MCQhard

The calculated spin only magnetic moment of Cr²⁺ ion is

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Match the Column I with Column II and mark the appropriate choice.

Match the Followingmedium

Which of the following sets of examples and geometry of the compounds is not correct?

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[Co(C₂O₄)₃]³⁻ is a diamagnetic complex because

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The charges x and y on the following ions are (i) [Co(NH₃)₆]Cl₃ (ii) [Fe(CN)₆]y⁻ (Oxidation state of Co is +3 and Fe is +2 in their respective complexes.)

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Which of the following sets of examples and geometry of the compounds is not correct?

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Which of the following statements is correct for [Mn(CN)₆]³⁻ according to valence bond theory?

MCQhard

The magnitude of CFSE (crystal field splitting energy, Δ₀) can be related to the configuration of d-orbitals in a coordination entity as

MCQmedium

IUPAC name of [Pt(NH₃)₂Cl(NO₂)] is :

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What is the coordination number of the central atom in a complex determined by?

MCQeasy

Which type of isomerism arises from the binding of an ambidentate ligand through different atoms?

MCQeasy

What determines the coordination number of the central atom in a coordination compound?

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What is the electronic configuration of the cobalt ion in the complex [Co(NH3)6]3+?

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What is the property of transition metal complexes that results in a wide range of colors?

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Which of the following statements about coordination compounds is correct?

MCQeasy

Which of the following statements about coordination compounds is correct?

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Assertion (A): In coordination chemistry, the term 'hydrate isomerism' is used when water molecules are involved as solvent molecules.

Reason (R): Solvate isomerism involves differences in whether a solvent molecule is directly bonded to the metal ion or is present as free solvent molecules.

Assertion Reasoneasy

Assertion (A): A coordination compound containing an ambidentate ligand can exhibit linkage isomerism.

Reason (R): The metal-carbon bond in metal carbonyls possesses both sigma and pi character.

Assertion Reasonmedium

Assertion (A): Double salts dissociate completely into simple ions in aqueous solutions.

Reason (R): Complex ions like [Fe(CN)6]4– do not dissociate into their constituent ions in water.

Assertion Reasonmedium

Assertion (A): Anionic ligands exert the greatest splitting effect in coordination compounds.

Reason (R): The crystal field model assumes ligands are point charges.

Assertion Reasonmedium

Assertion (A): The coordination number of a central metal atom is determined by the number of sigma bonds formed by ligands.

Reason (R): Pi bonds between ligands and the central metal atom do not contribute to the coordination number.

Assertion Reasonmedium

Assertion (A): The crystal field theory (CFT) fails to explain the covalent character of bonding in coordination compounds.

Reason (R): CFT assumes ligands are point charges leading to the highest splitting effect by anionic ligands.

Assertion Reasonhard

Assertion (A): The geometry of the complex ion [MnBr4]2– is tetrahedral.

Reason (R): The magnetic moment of the complex ion is 5.9 BM, indicating the presence of five unpaired electrons.

Assertion Reasonhard

Match Column-I with Column-II.

Column-IColumn-II
(a) Coordination Number 4(i) Octahedral
(b) Coordination Number 5(ii) Tetrahedral
(c) Coordination Number 6(iii) Trigonal bipyramidal
(d) Coordination Number 2(iv) Linear
Match the Followingeasy

What type of isomerism is exhibited by coordination compounds containing ambidentate ligands?

MCQeasy

What type of isomerism arises in coordination compounds containing ambidentate ligands?

MCQmedium

What type of isomerism involves complexes with the same chemical formula but different arrangements of atoms?

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What determines the coordination number of the central atom in a coordination compound?

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What determines the coordination number of a central atom in a coordination compound?

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What is the energy separation denoted by D o in crystal field theory for octahedral complexes?

MCQhard

What type of isomerism occurs in octahedral complexes of the formula [Ma3b3]?

MCQhard

Which type of isomerism arises when didentate ligands are present in complexes of the formula [MX2(L–L)2]?

MCQhard

Which of the following statements about coordination compounds is correct?

MCQeasy

Which of the following statements about coordination compounds is correct?

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Which of the following statements about the properties of coordination compounds is correct?

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Which of the following statements about ligand arrangement in coordination compounds is correct?

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