NEET Chemistry Isomerism in Complexes Match the Following Question
Match Column-I with Column-II.
| Column-I | Column-II |
|---|---|
| (a) Facial isomer | (i) Complex with linkage isomerism |
| (b) Meridional isomer | (ii) [Co(NH3)6][Cr(CN)6] |
| (c) Ambidentate ligand | (iii) [Co(NH3)3(NO2)3] |
| (d) Coordination isomer | (iv) NCS– ligand |
a-iii, b-ii, c-iv, d-i
a-i, b-iii, c-ii, d-iv
a-ii, b-i, c-iii, d-iv
a-ii, b-iv, c-i, d-iii
Correct Answer
Detailed Explanation
Facial and meridional isomers refer to the arrangement of ligands in octahedral complexes, specifically in [Co(NH3)3(NO2)3]. The ambidentate ligand NCS– can cause linkage isomerism, and coordination isomerism is exemplified by [Co(NH3)6][Cr(CN)6].
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