Chemistry-(general)

NEET Chemistry (general) MCQ Question

Type: MCQ-conceptual-Easy-Class 12

Which of the following statements about coordination compounds is correct?

A

Diamagnetic octahedral complexes have no unpaired electrons.

B

All octahedral complexes exhibit high spin configurations.

C

The geometry of a complex cannot be predicted from its magnetic behavior.

D

Cobalt in [Co(NH₃)₆]³⁺ is in the +2 oxidation state.

Correct Answer

Option A

Detailed Explanation

Statement A is correct because diamagnetic octahedral complexes, like [Co(NH₃)₆]³⁺, have no unpaired electrons, leading to their diamagnetic nature. Statement B is incorrect as not all octahedral complexes are high spin. Statement C is false since the geometry can often be predicted from magnetic behavior. Statement D is incorrect as cobalt in this complex is in the +3 oxidation state.

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