Chemistry-Crystal Field Theory

NEET Chemistry Crystal Field Theory Assertion Reason Question

Type: Assertion Reason-assertion-Medium-Class 12

Assertion (A): The geometry of [MnBr4]2– is tetrahedral. | Reason (R): The spin only magnetic moment of [MnBr4]2– is 5.9 BM, indicating the presence of five unpaired electrons.

A

Both A and R are true, and R is the correct explanation of A.

B

Both A and R are true, but R is not the correct explanation of A.

C

A is true, but R is false.

D

A is false.

Correct Answer

Option A

Detailed Explanation

Both the assertion and reason are correct. The NCERT context states that a magnetic moment of 5.9 BM indicates five unpaired electrons, which are consistent with a tetrahedral geometry for [MnBr4]2–.

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