Chemistry-Coordination Number

NEET Chemistry Coordination Number MCQ Question

Type: MCQ-conceptual-Medium-Class 12

Which of the following statements about coordination numbers is correct?

A

The coordination number of [Fe(C2O4)3]3– and [Co(en)3]3+ is 6 due to the presence of bidentate ligands.

B

The coordination number of [Ni(NH3)4]2+ is 6 because it has six ammonia ligands.

C

Coordination numbers can only be determined for octahedral complexes.

D

The coordination number of a complex is always equal to the number of ligands surrounding the central atom or ion.

Correct Answer

Option A

Detailed Explanation

Statement A is correct as both C2O4 2– and en are bidentate ligands that contribute to a coordination number of 6. Statement B is incorrect; the coordination number of [Ni(NH3)4]2+ is 4. Statement C is false because coordination numbers can apply to non-octahedral complexes as well. Statement D is misleading as the coordination number can exceed the number of ligands in certain cases involving bridging ligands.

Found an issue with this question?