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Chemistry-Order of Reaction

NEET Chemistry Order of Reaction Assertion Reason Question

Type: Assertion Reason-assertion-Hard-Class 12

Assertion (A): The half-life of a first order reaction is independent of the initial concentration of the reactants.

Reason (R): For a first order reaction, the rate constant k is directly proportional to the initial concentration of the reactants.

A

Both A and R are true and R is the correct explanation of A.

B

Both A and R are true but R is not the correct explanation of A.

C

A is true but R is false.

D

A is false but R is true.

Correct Answer

Option C

Detailed Explanation

The half-life of a first order reaction is indeed independent of the initial concentration, as shown by t1/2 = 0.693/k. However, the rate constant k is not dependent on the initial concentration.

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