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Chemistry-Rate of Reaction

NEET Chemistry Rate of Reaction Assertion Reason Question

Type: Assertion Reason-assertion-Hard-Class 12

Assertion (A): The rate constant of a first-order reaction is independent of the initial concentration of the reactants.

Reason (R): The half-life of a first-order reaction is directly proportional to the initial concentration of the reactants.

A

Both (A) and (R) are true, and (R) is the correct explanation of (A).

B

Both (A) and (R) are true, but (R) is not the correct explanation of (A).

C

(A) is true, but (R) is false.

D

(A) is false, but (R) is true.

Correct Answer

Option C

Detailed Explanation

The rate constant of a first-order reaction is indeed independent of the initial concentration, while the half-life is constant and not proportional to initial concentration, contradicting the reason.

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