Chemistry-(general)

NEET Chemistry (general) MCQ Question

Type: MCQ-numerical-Medium-Class 11

Given the equilibrium reactions for a dibasic acid H2XH_2X: H2X(aq)H+(aq)+HX(aq)H_2X(aq) \rightleftharpoons H^+(aq) + HX^-(aq) HX(aq)H+(aq)+X2(aq)HX^-(aq) \rightleftharpoons H^+(aq) + X^{2-}(aq) If Ka1=1.0×104K_{a1} = 1.0 \times 10^{-4} and Ka2=1.0×108K_{a2} = 1.0 \times 10^{-8}, what is the overall equilibrium constant KoverallK_{overall} for the reaction H2X(aq)2H+(aq)+X2(aq)H_2X(aq) \rightleftharpoons 2H^+(aq) + X^{2-}(aq)?

A

0×10120 \times 10^{-12}

B

0×1080 \times 10^{-8}

C

0×1040 \times 10^{-4}

D

0×1060 \times 10^{-6}

Correct Answer

Option A

Detailed Explanation

The overall equilibrium constant KoverallK_{overall} is the product of Ka1K_{a1} and Ka2K_{a2}. Hence, Koverall=1.0×104×1.0×108=1.0×1012K_{overall} = 1.0 \times 10^{-4} \times 1.0 \times 10^{-8} = 1.0 \times 10^{-12}.

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