AIPMT PRELIMS2008Chemistry-Organic Chemistry

AIPMT PRELIMS 2008 Chemistry Nucleophilic Substitution Reactions MCQ Question

Type: MCQ-conceptual-Medium-Class 12

In a Sₙ2 substitution reaction of the type R–Br⁺Cl⁻ → R–Cl⁺Br⁻ Which one of the following has the highest relative rate?

A

CH₃–C–CH₂Br

B

CH₃CH₂Br

C

CH₃CH₂CH₂Br

D

CH₃–CH–CH₂Br

Correct Answer

Option B

Detailed Explanation

In Sₙ2 reactions, primary alkyl halides react faster than secondary or tertiary due to less steric hindrance.

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