AIPMT PRELIMS2002Chemistry-Coordination Compounds

AIPMT PRELIMS 2002 Chemistry Complex Formation MCQ Question

Type: MCQ-conceptual-Medium-Class 12

CuSO₄ when reacts with KCN forms CuCN, which is insoluble in water. It is soluble in excess of KCN, due to formation of the following complex :-

A

K₂[Cu(CN)₄]

B

K₃[Cu(CN)₄]

C

CuCN₂

D

Cu[KCu(CN)₄]

Correct Answer

Option B

Detailed Explanation

In excess KCN, CuCN forms the soluble complex K₂[Cu(CN)₄], allowing it to dissolve.

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