AIPMT PRELIMS2001Chemistry-Thermodynamics

AIPMT PRELIMS 2001 Chemistry Gibbs Free Energy MCQ Question

Type: MCQ-conceptual-Medium-Class 11

PbO₂ → PbO [ΔG₂₉₈ < 0] , SnO₂ → SnO [ΔG₂₉₈ > 0] Most probable oxidation state of Pb & Sn will be :

A

Pb⁺⁴, Sn⁻²

B

Pb⁺⁴, Sn⁻²

C

Pb²⁺, Sn⁻²

D

Pb²⁺, Sn⁺⁴

Correct Answer

Option D

Detailed Explanation

The negative ΔG for PbO₂ to PbO indicates Pb prefers to be in the +2 oxidation state, while the positive ΔG for SnO₂ to SnO indicates Sn prefers to be in the +4 state.

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