AIPMT PRELIMS2012Chemistry-Thermodynamics

AIPMT PRELIMS 2012 Chemistry Enthalpy and Internal Energy MCQ Question

Type: MCQ-numerical-Hard-Class 11

Standard enthalpy of vaporisation ΔvapH⁰ for water at 100°C is 40.66 kJmol⁻¹. The internal energy of vaporisation of water at 100°C (in kJ mol⁻¹) is

A

+40.66

B

+37.56

C

-43.76

D

+43.76

Correct Answer

Option B

Detailed Explanation

Using the relation ΔE = ΔH - PΔV, the internal energy change is calculated as 37.56 kJ mol⁻¹.

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