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AIPMT PRELIMS2003Chemistry-Chemical Equilibrium

AIPMT PRELIMS 2003 Chemistry Equilibrium Constants MCQ Question

Type: MCQ-conceptual-Hard-Class 11

The following equilibria are given: N2+3H2⇌2NH3,K1\text{N}_2 + 3\text{H}_2 \rightleftharpoons 2\text{NH}_3, \text{K}_1 N2+O2⇌2NO,K2\text{N}_2 + \text{O}_2 \rightleftharpoons 2\text{NO}, \text{K}_2 H2+12O2⇌H2O,K3\text{H}_2 + \frac{1}{2}\text{O}_2 \rightleftharpoons \text{H}_2\text{O}, \text{K}_3 The equilibrium constant of the reaction 2NH3+52O2⇌2NO+3H2O2\text{NH}_3 + \frac{5}{2}\text{O}_2 \rightleftharpoons 2\text{NO} + 3\text{H}_2\text{O} in terms of K1,K2\text{K}_1, \text{K}_2 and K3\text{K}_3 is:

A

K1K1K3\text{K}_1 \text{K}_1 \text{K}_3

B

K1K2K3\frac{\text{K}_1 \text{K}_2}{\text{K}_3}

C

K1K32K2\frac{\text{K}_1 \text{K}_3^2}{\text{K}_2}

D

K2K33K1\frac{\text{K}_2 \text{K}_3^3}{\text{K}_1}

Correct Answer

Option D

Detailed Explanation

The equilibrium constant for the overall reaction is derived by combining the given equilibria. The expression is K2K33K1\frac{\text{K}_2 \text{K}_3^3}{\text{K}_1}.

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