AIIMS2008Chemistry-Organic Chemistry

AIIMS 2008 Chemistry Electrophilic Substitution Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 11

Assertion: Phenol is more reactive than benzene towards electrophilic substitution reaction.

Reason: In the case of phenol, the intermediate carbocation is more resonance stabilised.

A

Both Assertion and Reason are true and Reason is the correct explanation of Assertion.

B

Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.

C

Assertion is true but Reason is false.

D

Both Assertion and Reason are false.

Correct Answer

Option C

Detailed Explanation

-OH group shows +M effect and is an activating group, moreover the arenium ion of phenolic substitution is more stable.

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