AIIMS2019Chemistry-Organic Chemistry

AIIMS 2019 Chemistry Alkenes MCQ Question

Type: MCQ-conceptual-Medium-Class 11

Assertion: In trans-pent-2-ene, net dipole moment is non zero.

[Image: Chemical structure of trans-pent-2-ene]

Reason: The dipole moments of CCH3\text{C}-\text{CH}_3 and CCH2CH3\text{C}-\text{CH}_2\text{CH}_3 bonds are not equal.

Question diagram
A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option A

Detailed Explanation

In trans-pent-2-ene, the molecular geometry leads to different electronegativities between the C−CH₃ and C−C₂H₅ bonds, resulting in unequal bond dipoles. This asymmetry in bond dipoles contributes to a net dipole moment, making the molecule polar. Option B is incorrect because it implies that the dipole moment is zero, which contradicts the observed molecular structure. Options C and D are not applicable as the dipole moment can be determined based on the molecular geometry and bond characteristics.

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