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AIIMS2019Chemistry-Chemical Bonding and Molecular Structure

AIIMS 2019 Chemistry Hybridization MCQ Question

Type: MCQ-conceptual-Medium-Class 11

The ion that has sp³d² hybridization for the central atom is:

A

[Cl₄]⁻

B

[Cl₂]⁻

C

[IF₆]⁻

D

[BrF₂]⁻

Correct Answer

Option A

Detailed Explanation

The ion [Cl₄]⁻ has a central chlorine atom that undergoes sp³d² hybridization, resulting in an octahedral geometry with six electron pairs (four bonding pairs and two lone pairs). In contrast, [Cl₂]⁻ involves only two chlorine atoms and does not require hybridization beyond sp³, while [IF₆]⁻, although having an octahedral shape, involves iodine and not chlorine. Lastly, [BrF₂]⁻ has a central bromine atom with sp³ hybridization, leading to a bent molecular shape, which does not utilize the d-orbitals necessary for sp³d² hybridization.

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