STANDARDChemistry-Amines

STANDARD Chemistry Reactivity of Amines Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: Aniline does not undergo Friedel-Crafts reaction. Reason: Friedel-Crafts reaction is an electrophilic substitution reaction.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option B

Detailed Explanation

Aniline does not undergo Friedel-Crafts reaction due to salt formation with aluminium chloride, the Lewis acid, which is used as a catalyst. Due to this, nitrogen of aniline acquires a positive charge and hence acts as a strong deactivating group for further reaction.

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