STANDARDChemistry-Alcohols, Phenols and Ethers

STANDARD Chemistry Properties of Phenols MCQ Question

Type: MCQ-conceptual-Medium-Class 12

o-Nitrophenol is less soluble in water than p- and m-nitrophenols because

A

o-nitrophenol shows intramolecular H-bonding

B

o-nitrophenol shows intermolecular H-bonding

C

melting point of o-nitrophenol is lower than those of m- and p-isomers

D

o-nitrophenol is more volatile in steam than those of m- and p-isomers.

Correct Answer

Option A

Detailed Explanation

o-Nitrophenol forms intramolecular hydrogen bonds, reducing its ability to form hydrogen bonds with water, thus decreasing its solubility compared to p- and m-nitrophenols.

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