STANDARDChemistry-Thermochemistry

STANDARD Chemistry Enthalpy of Formation MCQ Question

Type: MCQ-numerical-Medium

rU° of combustion of CH₄(g) at certain temperature is −393 kJ mol⁻¹. The value of ΔfH° is

A

Zero

B

< ΔfU°

C

ΔfU°

D

equal to ΔfU°

Correct Answer

Option B

Detailed Explanation

The balanced equation for combustion of methane is CH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(l). Here, Δng = 1 − 3 = −2. rH° = ΔfU° + ΔngRT; ΔfH° = −393 − 2RT. Therefore, ΔfH° < ΔfU°.

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