STANDARDChemistry-Organic Chemistry

STANDARD Chemistry Electrophilic Aromatic Substitution MCQ Question

Type: MCQ-conceptual-Medium

The electrophile, E⁺ attacks the benzene ring to generate the intermediate σ-complex. Which σ-complex is of lowest energy?

A

(1)

B

(2)

C

(3)

D

(4)

Correct Answer

Option D

Detailed Explanation

The σ-complex with the lowest energy is the one where the positive charge is delocalized over the most stable positions. In this case, the complex shown in option 4 is the most stable due to resonance stabilization.

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