STANDARDChemistry-Organic Chemistry

STANDARD Chemistry Acid Strength Multiple Correct Question

Type: Multiple Correct-conceptual-Hard

Which of the following is the correct order of acidity of carboxylic acids? (i) Cl₃CCOOH > Cl₂CHCOOH > ClCH₂COOH (ii) CH₃CH₂COOH > (CH₃)₂CHCOOH > (CH₃)₃CCOOH (iii) F₂CHCOOH > FCH₂COOH > ClCH₂COOH

A

(i) and (ii)

B

(ii) and (iii)

C

(i) and (iii)

D

(i), (ii) and (iii)

Correct Answer

Option D

Detailed Explanation

The strength of the acid increases with the inductive effect of the electronegative group attached to it (–I effect). The strength of the acid decreases with the presence of an electron-releasing group.

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