STANDARDChemistry-Aromatic Compounds

STANDARD Chemistry Reactions of Diazonium Salts MCQ Question

Type: MCQ-conceptual-Hard

Mark the correct route of the conversion of p-chloroaniline to p-chlorobenzylamine.

Question diagram
A

i-Alkylation ii-KCN iii-H₂/Pt

B

i-Diazotisation ii-CuCN iii-H₂/Pt

C

i-Oxidation ii-H₂/Pt iii-Hydrolysis

D

i-Diazotisation ii-H₂O/H⁺ iii-Sn/HCl

Correct Answer

Option B

Detailed Explanation

The conversion involves diazotisation of p-chloroaniline to form a diazonium salt, followed by replacement with CuCN to form a nitrile, and finally reduction with H₂/Pt to form p-chlorobenzylamine.

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