STANDARDChemistry-Alcohols, Phenols and Ethers

STANDARD Chemistry Acidity of Alcohols MCQ Question

Type: MCQ-conceptual-Medium-Class 12

The correct sequence of decreasing acidity is

A

(CH₃)₃COH > (CH₃)₂CHOH > C₂H₅OH > CH₃OH

B

CH₃OH > C₂H₅OH > (CH₃)₂CHOH > (CH₃)₃COH

C

C₂H₅OH > CH₃OH > (CH₃)₃COH > (CH₃)₂CHOH

D

(CH₃)₂CHOH > (CH₃)₃COH > C₂H₅OH > CH₃OH

Correct Answer

Option B

Detailed Explanation

Acidity decreases with increasing alkyl group size due to the electron-donating effect, which destabilizes the alkoxide ion. Methanol is the most acidic, followed by ethanol, isopropanol, and tert-butanol.

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