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RE-NEET2026Chemistry-Coordination Compounds

RE-NEET 2026 Chemistry Crystal Field Theory MCQ Question

Type: MCQ-fact-Medium-Class 12

According to crystal field theory, the correct order of ligands with respect to their decreasing order of field strength is

A

CO > H₂O > NH₃ > Cl⁻

B

Cl⁻ > H₂O > NH₃ > CO

C

Cl⁻ > NH₃ > H₂O > CO

D

CO > NH₃ > H₂O > Cl⁻

Correct Answer

Option D

Detailed Explanation

Chemistry | Coordination Compounds

Topic: Crystal Field Theory Difficulty: 🟡 Medium

✅ Ans: D

Field strength follows the spectrochemical series:

CO>NH3>H2O>Cl−\boxed{CO>NH_3>H_2O>Cl^-}

Why? Stronger ligand → causes greater splitting (Δ)(\Delta) of d-orbitals.

  • CO → strong-field ligand
  • NH₃ → stronger than H₂O
  • H₂O → stronger than Cl⁻
  • Cl⁻ → weak-field ligand

❌ Other options

They are incorrect because they reverse the known order of ligand field strength.

📌 NCERT: Ligands can be arranged in a spectrochemical series according to their increasing field strength.

🧠 Easy recall: CO > NH₃ > H₂O > Cl⁻ → Strong → Weak

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