Chemistry-(general)

NEET Chemistry (general) MCQ Question

Type: MCQ-conceptual-Hard-Class 12

Which of the following statements about the preparation of aldehydes and ketones is correct?

A

Aldehydes can be prepared from the reduction of nitriles using stannous chloride.

B

Ketones can be directly obtained from the hydration of alkenes without any catalysts.

C

The Rosenmund reduction is used to convert carboxylic acids to aldehydes.

D

Ethyne can yield acetaldehyde only in the absence of catalysts.

Correct Answer

Option A

Detailed Explanation

Statement A is correct as nitriles can be reduced to aldehydes via the Stephen reaction, which involves stannous chloride. Statements B and D are incorrect because alkenes require catalysts for hydration, and ethyne produces acetaldehyde with a catalyst present. Statement C is also incorrect as the Rosenmund reduction involves acyl chlorides converting to aldehydes, not carboxylic acids.

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