Chemistry-Substitution Reactions

NEET Chemistry Substitution Reactions MCQ Question

Type: MCQ-conceptual-Hard-Class 11

Which of the following statements about substitution reactions of benzene is correct?

A

The sigma complex loses aromatic character when it forms an arenium ion.

B

The product of halogenation is always a fully hydrogenated benzene derivative.

C

Aromatic character is restored before the release of the proton in the substitution mechanism.

D

Chlorine can substitute in benzene without the need for ultraviolet light.

Correct Answer

Option A

Detailed Explanation

The sigma complex or arenium ion loses its aromatic character because delocalisation of electrons stops at the sp3 hybridised carbon, as stated in the context provided. Other options reflect misconceptions about the substitution mechanism.

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