Chemistry-Substitution Reactions

NEET Chemistry Substitution Reactions Assertion Reason Question

Type: Assertion Reason-assertion-Hard-Class 11

Assertion (A): In electrophilic substitution reactions on benzene, halogens act as deactivating groups. | Reason (R): Halogens decrease the overall electron density on the benzene ring but increase electron density at ortho and para positions due to resonance.

A

Both A and R are true and R is the correct explanation of A.

B

Both A and R are true but R is not the correct explanation of A.

C

A is true but R is false.

D

A is false.

Correct Answer

Option A

Detailed Explanation

Halogens are deactivating because they decrease the overall electron density on the benzene ring, but due to resonance, they direct substitution to ortho and para positions, supporting the assertion and reason.

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