NEET2022Chemistry-Alcohols, Phenols and Ethers

NEET 2022 Chemistry Lucas Test Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Given below are two statements:

Statement I: In Lucas test, primary, secondary and tertiary alcohols are distinguished on the basis of their reactivity with conc. HCl + ZnCl₂ known as Lucas reagent.

Statement II: Primary alcohols are most reactive and immediately produce turbidity at room temperature on reaction with Lucas reagent.

In the light of the above statements, choose the most appropriate answer from the options given below:

A

Statement I is correct but Statement II is incorrect.

B

Statement I is incorrect but Statement II is correct.

C

Both Statement I and Statement II are correct.

D

Both Statement I and Statement II are incorrect.

Correct Answer

Option A

Detailed Explanation

In the Lucas test, tertiary alcohols react fastest, producing turbidity immediately, while primary alcohols react slowly. Therefore, Statement I is correct, but Statement II is incorrect.

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