NEET2025Chemistry-Acidity of Carboxylic Acids

NEET 2025 Chemistry Aliphatic Acids MCQ Question

Type: MCQ-conceptual-Medium-Class 12

The correct order of decreasing acidity of the following aliphatic acids is :

A

(CH₃)₃CCOOH > (CH₃)₂CHCOOH > CH₃COOH > HCOOH

B

CH₃COOH > (CH₃)₂CHCOOH > (CH₃)₃CCOOH > HCOOH

C

HCOOH > CH₃COOH > (CH₃)₂CHCOOH > (CH₃)₃CCOOH

D

HCOOH > (CH₃)₃CCOOH > (CH₃)₂CHCOOH > CH₃COOH

Correct Answer

Option C

Detailed Explanation

Acidity decreases with increasing alkyl substitution due to the electron-donating effect of alkyl groups. Thus, formic acid (HCOOH) is the most acidic, followed by acetic acid (CH₃COOH), then isopropanoic acid ((CH₃)₂CHCOOH), and finally tert-butanoic acid ((CH₃)₃CCOOH).

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