AIPMT PRELIMS2007Chemistry-Organic Chemistry

AIPMT PRELIMS 2007 Chemistry Stereochemistry MCQ Question

Type: MCQ-conceptual-Medium-Class 11

CH₃—CHCl—CH₂—CH₃ has a chiral centre. which one of the following represents its R⁻configuration?

A

C2H5HCCH3Cl\begin{array}{c} \text{C}_2\text{H}_5 \\ | \\ \text{H} - \text{C} - \text{CH}_3 \\ | \\ \text{Cl} \end{array}

B

C2H5ClCCH3H\begin{array}{c} \text{C}_2\text{H}_5 \\ | \\ \text{Cl} - \text{C} - \text{CH}_3 \\ | \\ \text{H} \end{array}

C

CH3HCClC2H5\begin{array}{c} \text{CH}_3 \\ | \\ \text{H} - \text{C} - \text{Cl} \\ | \\ \text{C}_2\text{H}_5 \end{array}

D

C2H5H3CCClH\begin{array}{c} \text{C}_2\text{H}_5 \\ | \\ \text{H}_3\text{C} - \text{C} - \text{Cl} \\ | \\ \text{H} \end{array}

Correct Answer

Option a

Detailed Explanation

The R/S configuration is determined by the Cahn-Ingold-Prelog priority rules. The configuration is R if the sequence is clockwise.

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