AIPMT PRELIMS2009Chemistry-Chemical Equilibrium

AIPMT PRELIMS 2009 Chemistry Equilibrium Constant MCQ Question

Type: MCQ-numerical-Medium-Class 11

The dissociation constants for acetic acid and HCN at 25°C are 1.5 × 10⁻⁵ and 4.5 × 10⁻¹⁰ respectively. The equilibrium constant for the equilibrium

CN⁻ + CH₃COOH ⇌ HCN + CH₃COO⁻ would be:

A

3.0 × 10⁻⁵

B

3.0 × 10⁻⁴

C

3.0 × 10⁴

D

3.0 × 10⁵

Correct Answer

Option C

Detailed Explanation

The equilibrium constant Kₐ for CN⁻ + CH₃COOH ⇌ CH₃COO⁻ + HCN is calculated as 1.5 × 10⁻⁵ / 4.5 × 10⁻¹⁰ = 3.33 × 10⁴.

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