AIPMT PRELIMS2002Chemistry-Ionic Equilibrium

AIPMT PRELIMS 2002 Chemistry Buffer Solutions MCQ Question

Type: MCQ-numerical-Medium-Class 11

Solution of 0.1 N NH₄OH and 0.1 N NH₄Cl has pH 9.25, Then find out pkb of NH₄OH :-

A

9.25

B

4.75

C

3.75

D

8.25

Correct Answer

Option B

Detailed Explanation

Using the Henderson-Hasselbalch equation for a buffer solution: pH = pKa + log([base]/[acid]). Here, pH = 9.25, pKa =¹⁴⁻ pkb, so pkb = 4.75.

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