AIPMT MAIN2008Chemistry-Coordination Compounds

AIPMT MAIN 2008 Chemistry Crystal Field Theory MCQ Question

Type: MCQ-conceptual-Hard-Class 12

In which of the following coordination entities the magnitude of ΔO (CFSE in octahedral field) will be maximum (at. no. Co = 27)?

A

[Co (C₂O₄)₃]³⁻

B

[Co(H₂O)₆]³⁺

C

[Co(NH₃)₆]³⁺

D

[Co(CN)₆]³⁻

Correct Answer

Option D

Detailed Explanation

The ligand CN⁻ is a strong field ligand and causes a large splitting of d-orbitals, resulting in a high CFSE.

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