AIIMS2006Physics-Gaseous State

AIIMS 2006 Physics Ideal Gas Law MCQ Question

Type: MCQ-conceptual-Medium-Class 11

Two balloons are filled, on with pure He gas and other by air, respectively. If the pressure and temperature of these balloons are same then the number of molecules per unit volume is

A

more in the He filled balloon

B

same in both balloons

C

more in air filled balloon

D

in the ratio of 1 : 4

Correct Answer

Option B

Detailed Explanation

To solve the problem, we need to apply the Ideal Gas Law, which is given by the formula:

PV=nRTPV = nRT

where:

  • PP is the pressure,
  • VV is the volume,
  • nn is the number of moles of gas,
  • RR is the universal gas constant,
  • TT is the temperature in Kelvin.

Explanation of the Correct Answer

Given that both balloons are at the same pressure PP and temperature TT, we can derive the number of molecules per unit volume (which is the number density of the gas) in each balloon.

  1. Calculating Number of Moles: From the Ideal Gas Law, we can rearrange the equation to find the number of moles nn:

    n=PVRTn = \frac{PV}{RT}
  2. Calculating Number of Molecules: The number of molecules NN can be calculated from the number of moles using Avogadro's number NAN_A:

    N=n×NA=PVRT×NAN = n \times N_A = \frac{PV}{RT} \times N_A
  3. Number Density: The number density ndn_d (number of molecules per unit volume) can be expressed as:

    nd=NV=PRT×NAn_d = \frac{N}{V} = \frac{P}{RT} \times N_A

Since the pressure PP and temperature TT are the same for both balloons, the number density ndn_d will also be the same for both helium (He) and air.

Thus, the correct answer is:

B) same in both balloons.

Clarification of Incorrect Options

  • Option A: more in the He filled balloon: This option is incorrect because, although helium has a lower molar mass than air, the number density depends on pressure and temperature, which are equal for both balloons. Hence, the number of molecules per unit volume is the same.

  • Option C: more in air filled balloon: This is also incorrect for the same reason as Option A. The number density is determined by PP and TT, both of which are the same in this scenario.

  • Option D: in the ratio of 1:4: This option implies a specific numerical relationship that does not apply. The ratio of number densities is not determined by the type of gas in this context, as the pressure and temperature are constants.

Conclusion

In conclusion, the number of molecules per unit volume in both balloons is the same because they are held at the same pressure and temperature. The Ideal Gas Law confirms that under these conditions, the number density is independent of the type of gas, provided it behaves ideally. Thus, the correct answer is B.

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