AIIMS2018Chemistry-Phosphorus and its Compounds

AIIMS 2018 Chemistry Allotropes of Phosphorus MCQ Question

Type: MCQ-conceptual-Medium-Class 12

Which of the following statements is incorrect?

A

Red P is toxic

B

White ‘P’ is highly soluble in CS₂

C

Black ‘P’ is thermodynamically most stable

D

White ‘P’ is soluble in NaOH and evolves PH₃

Correct Answer

Option A

Detailed Explanation

Option A is incorrect because red phosphorus (Red P) is not considered toxic; it is relatively safe compared to white phosphorus (White P), which is highly toxic and can cause severe health issues upon exposure. Option B is correct as white phosphorus is indeed highly soluble in carbon disulfide (CS₂), while option C is accurate since black phosphorus is the most thermodynamically stable allotrope of phosphorus. Option D is also true, as white phosphorus reacts with sodium hydroxide (NaOH) to produce phosphine (PH₃) and other products, demonstrating its reactivity in basic conditions.

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