AIIMS2018Chemistry-General Principles and Processes of Isolation of Elements

AIIMS 2018 Chemistry Reactions of Metals with Acids Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: When a metal is treated with concentration HNO₃ it generally yields a nitrate, NO₂ and H₂O. Reason: Conc. HNO₃ reacts with metal and first produces a metal nitrate and nascent hydrogen, the nascent hydrogen then further reduces HNO₃ to NO₂.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If both assertion and reason are false

D

If both assertion and reason are false

Correct Answer

Option A

Detailed Explanation

Option A is correct because both the assertion and reason accurately describe the reaction of metals with concentrated HNO₃. The assertion states that this reaction produces a metal nitrate, NO₂, and H₂O, which is true, as concentrated nitric acid oxidizes metals, yielding these products. The reason explains that nascent hydrogen is generated during the reaction, which then reduces HNO₃ to NO₂, correctly linking the processes involved.

Options B, C, and D are incorrect because they either misrepresent the relationship between the assertion and reason or incorrectly state that one or both are false. In reality, both statements are true and the reason provides a valid explanation for the assertion.

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