AIIMS2018Chemistry-Qualitative Analysis

AIIMS 2018 Chemistry Brown Ring Test Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: The transition of electrons n3n2n_3 \rightarrow n_2 in H-atom will emit radiation of higher frequency than n4n3n_4 \rightarrow n_3.

Reason: Principal shells n2n_2 and n3n_3 have lower energy than n4n_4.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option B

Detailed Explanation

In the Brown ring test, the assertion that Fe²⁺ is oxidized to Fe³⁺ is true, as this reaction is essential for the formation of the brown ring complex with [Fe(H₂O)₅NO]²⁺. However, the reason stating that NO₃⁻ is reduced to NO is false because, in this context, the reduction actually involves the conversion of NO₃⁻ to NO₂ or other nitrogen oxides, not directly to NO. Therefore, while both the assertion and reason are true statements in different contexts, the reason does not correctly explain the assertion, making option B the appropriate choice. Options A and C are incorrect because they misrepresent the relationship between the assertion and reason, while option D incorrectly states that the assertion is false.

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