AIIMS 2018 Chemistry Brown Ring Test Assertion Reason Question
Assertion: The transition of electrons in H-atom will emit radiation of higher frequency than .
Reason: Principal shells and have lower energy than .
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Correct Answer
Detailed Explanation
In the Brown ring test, the assertion that Fe²⁺ is oxidized to Fe³⁺ is true, as this reaction is essential for the formation of the brown ring complex with [Fe(H₂O)₅NO]²⁺. However, the reason stating that NO₃⁻ is reduced to NO is false because, in this context, the reduction actually involves the conversion of NO₃⁻ to NO₂ or other nitrogen oxides, not directly to NO. Therefore, while both the assertion and reason are true statements in different contexts, the reason does not correctly explain the assertion, making option B the appropriate choice. Options A and C are incorrect because they misrepresent the relationship between the assertion and reason, while option D incorrectly states that the assertion is false.
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