AIIMS2014Chemistry-Atomic Structure
AIIMS 2014 Chemistry Atomic Structure MCQ Question
Type: MCQ-conceptual-Medium-Class 12
The stability of ferric ion is due to
A
half-filled d-orbitals
B
half-filled f-orbitals
C
completely filled d-orbitals
D
completely filled f-orbitals
Correct Answer
Option A
Detailed Explanation
The stability of the ferric ion (Fe³⁺) is primarily attributed to the presence of half-filled d-orbitals. In transition metals, half-filled d-orbitals provide enhanced stability due to symmetrical electron distribution and reduced electron-electron repulsion, which leads to a lower energy state. This stability is particularly significant in the case of Fe³⁺, where the electron configuration results in a half-filled d-subshell (d⁵) when considering the overall stability of its oxidation state.
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