AIIMS2014Chemistry-Atomic Structure

AIIMS 2014 Chemistry Atomic Structure MCQ Question

Type: MCQ-conceptual-Medium-Class 12

The stability of ferric ion is due to

A

half-filled d-orbitals

B

half-filled f-orbitals

C

completely filled d-orbitals

D

completely filled f-orbitals

Correct Answer

Option A

Detailed Explanation

The stability of the ferric ion (Fe³⁺) is primarily attributed to the presence of half-filled d-orbitals. In transition metals, half-filled d-orbitals provide enhanced stability due to symmetrical electron distribution and reduced electron-electron repulsion, which leads to a lower energy state. This stability is particularly significant in the case of Fe³⁺, where the electron configuration results in a half-filled d-subshell (d⁵) when considering the overall stability of its oxidation state.

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