AIIMS2018Chemistry-Qualitative Analysis

AIIMS 2018 Chemistry Brown Ring Test Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: Fe³⁺ is not valid for Brown Ring Test. Reason: Because NO₃⁻ first convert into NO₂⁻

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option C

Detailed Explanation

Fe³⁺ is indeed not valid for the Brown Ring Test, which is specifically used to detect Fe²⁺ ions in the presence of nitrate ions (NO₃⁻) that reduce to form a complex with Fe²⁺. However, the reason provided is incorrect because NO₃⁻ does not convert to NO₂⁻ in this context; it remains as NO₃⁻ during the test. Option A is incorrect because the reason does not explain the assertion, while Option B is incorrect as the reason is false. Option D is also incorrect since the assertion is true.

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