AIIMS2019Chemistry-Organic Chemistry

AIIMS 2019 Chemistry Electrophilic Aromatic Substitution MCQ Question

Type: MCQ-conceptual-Medium-Class 12

The complete reaction is shown below. From the above reaction, it is clear that the amino group is o-p-directing in nature.

Question diagram

Correct Answer

Option C

Detailed Explanation

In electrophilic aromatic substitution reactions, an amino group (–NH₂) is an o-p-directing group due to its ability to donate electron density to the aromatic ring through resonance, stabilizing the positive charge in the intermediate carbocation formed during the reaction. Option C illustrates the amino group positioned in such a way that it enhances the reactivity of ortho and para positions, making them more favorable for substitution. Other options may depict substituents that are either deactivating or meta-directing, which do not enhance the reactivity at the ortho and para positions, thus failing to demonstrate the o-p-directing nature of the amino group.

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