AIIMS2018Chemistry-Elimination Reactions

AIIMS 2018 Chemistry β-Dehydrohalogenation Assertion Reason Question

Type: Assertion Reason-conceptual-Medium-Class 12

Assertion: β-dehydrohalogenation of alkyl halides is anti elimination in which bond breaking and bond forming occur simultaneously. Reason: β-Dehydrohalogenation of alkyl halides gives Saytzeff product.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Correct Answer

Option A

Detailed Explanation

Option A is correct because the assertion accurately describes β-dehydrohalogenation as an anti elimination process where the breaking of the C–X bond (X being a halogen) and the forming of the C=C double bond occur simultaneously, consistent with the mechanism of E2 reactions. The reason is also true, as β-dehydrohalogenation typically leads to the Saytzeff product, which is the more substituted alkene favored due to greater stability.

Options B and C are incorrect because while both the assertion and reason are true, the reason directly explains the assertion by linking the mechanism to the product outcome. Option D is incorrect as both statements are valid.

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