AIIMS2019Chemistry-Coordination Compounds

AIIMS 2019 Chemistry Hybridization and Geometry MCQ Question

Type: MCQ-conceptual-Medium-Class 12

When Ag+\text{Ag}^+ reacts with excess of sodium-thio sulphate then the obtained species having charge & geometry respectively will be?

A

–3, Linear

B

–2, tetrahedral

C

–1, square planer

D

–3, square planar

Correct Answer

Option B

Detailed Explanation

The complex ion [Ag(S2O3)2]3[Ag(S₂O₃)₂]^{3-} features silver (Ag) coordinated to two thiosulfate ligands (S₂O₃²⁻), resulting in a coordination number of 2. This arrangement leads to sp hybridization, which allows for linear geometry, as the two ligands are positioned 180° apart. Option A is incorrect because sp hybridization corresponds to a coordination number of 2, not sp², which is associated with a coordination number of 3 and trigonal planar geometry. Options C and D are also incorrect; sp³ hybridization corresponds to a tetrahedral geometry (coordination number 4), while dsp² hybridization is relevant for square planar complexes (coordination number 4 or 6).

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